CRYSTAL-STRUCTURE OF THE HEMITOLUENE SOLVATE OF RACEMIC PYRIDYL)CHLORO(TRI-N-PROPYLPHOSPHINE)RUTHENIUM(II) PERCHLORATE, A SPECIES WITH DISORDERED PPR3 AND TOLUENE MOIETIES

Authors
CHURCHILL MR SEE RF BESSEL CA TAKEUCHI KJ
Citation
Mr. Churchill et al., CRYSTAL-STRUCTURE OF THE HEMITOLUENE SOLVATE OF RACEMIC PYRIDYL)CHLORO(TRI-N-PROPYLPHOSPHINE)RUTHENIUM(II) PERCHLORATE, A SPECIES WITH DISORDERED PPR3 AND TOLUENE MOIETIES, Journal of chemical crystallography, 26(10), 1996, pp. 667-675
Citations number
16
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
26
Issue
10
Year of publication
1996
Pages
667 - 675
Database
ISI
SICI code
1074-1542(1996)26:10<667:COTHSO>2.0.ZU;2-I
Abstract
The complex cis-[Ru(bpy)(2)(PPr3Cl+][ClO4-]. 0.5 (toluene) crystallize s as a racemate in the monoclinic space group P2(1)/n. Both the PPr3 l igand and the toluene of crystallization are subject to disorder. Ruth enium-ligand distances are: Ru-PPr3=2.348(2) Angstrom, Ru-Cl=2.426(2) Angstrom and Ru-N(bpy)=2.035(6)-2.112(5) Angstrom.