REACTIONS OF METHACRYLOYL ISOCYANATE WITH IMINES DERIVED FROM KETONESAND ALKYL AMINES

Authors
TSUGE O HATTA T KUWATA M YAMASHITA T KAKEHI A
Citation
O. Tsuge et al., REACTIONS OF METHACRYLOYL ISOCYANATE WITH IMINES DERIVED FROM KETONESAND ALKYL AMINES, Heterocycles, 43(10), 1996, pp. 2083-2090
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
43
Issue
10
Year of publication
1996
Pages
2083 - 2090
Database
ISI
SICI code
0385-5414(1996)43:10<2083:ROMIWI>2.0.ZU;2-A
Abstract
The reactions of methacryloyl isocyanate (MAI) with imines derived fro m ketones and alkyl amines led to the formation of the corresponding 2 H-1,3,5-oxadiazin-4(3H)-one, 1,3-oxazine, piperidinedione, and/or 1-al kyl-1-alkenyl-3-methacryloylurea, whose relative yields greatly depend ed on the reaction conditions as well as the nature of imine. The latt er three compounds correspond to products arising from the reacion of MAI with enamine tautomers of imines.