THE FACILE SYNTHESIS OF CYCLOPENTANOID ANTIBIOTIC KJELLMANIANONE

Authors
DEMIR AS TANYELI C GULBEYAZ V AKGUL H
Citation
As. Demir et al., THE FACILE SYNTHESIS OF CYCLOPENTANOID ANTIBIOTIC KJELLMANIANONE, Turkish journal of chemistry, 20(3), 1996, pp. 244-248
Citations number
18
Categorie Soggetti
Chemistry,"Engineering, Chemical
Journal title
Turkish journal of chemistry → ACNP
ISSN journal
13000527
Volume
20
Issue
3
Year of publication
1996
Pages
244 - 248
Database
ISI
SICI code
1300-0527(1996)20:3<244:TFSOCA>2.0.ZU;2-Z
Abstract
The synthesis of cyclopentanoid antibiotic Kjellmanianone is described in this study. The C-acylation of lithium enolates of 3-Methoxycyclop entenone by N-carbomethoxyimidazole or methylcyanoformate beta-ketoest er, which when oxidized with Mn(III) acetate produces kjellmanianone i n good yield.