SYNTHESIS OF SEVERAL NOVEL OPTICALLY-ACTIVE NITROXYL RADICALS

Authors
BRASLAU R KUHN H BURRILL LC LANHAM K STENLAND CJ
Citation
R. Braslau et al., SYNTHESIS OF SEVERAL NOVEL OPTICALLY-ACTIVE NITROXYL RADICALS, Tetrahedron letters, 37(44), 1996, pp. 7933-7936
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
44
Year of publication
1996
Pages
7933 - 7936
Database
ISI
SICI code
0040-4039(1996)37:44<7933:SOSNON>2.0.ZU;2-H
Abstract
Optically active nitroxyl radicals are prepared from enantiomerically pure bicyclic terpenoids. (-)-Camphoxyl radical (-)-4 derived from com mercially available oxazolidinone (-)-1 and (+)-camphoxyl radical (+)- 4 derived from (-)-camphene are readily prepared, conformationally rig id, enantiomeric nitroxyl radicals. (-)-Camphorsulphonic acid is used to prepare two additional optically active nitroxyl radicals 9 and 12. Copyright (C) 1996 Elsevier Science Ltd