SULFOXIDE-CONTROLLED S(N)2' DISPLACEMENTS BETWEEN CYANOCUPRATES AND EPOXY VINYL SULFOXIDES

Authors
MARINO JP ANNA LJ DELAPRADILLA RF MARTINEZ MV MONTERO C VISO A
Citation
Jp. Marino et al., SULFOXIDE-CONTROLLED S(N)2' DISPLACEMENTS BETWEEN CYANOCUPRATES AND EPOXY VINYL SULFOXIDES, Tetrahedron letters, 37(44), 1996, pp. 8031-8034
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
44
Year of publication
1996
Pages
8031 - 8034
Database
ISI
SICI code
0040-4039(1996)37:44<8031:SSDBCA>2.0.ZU;2-4
Abstract
Readily available enantiomerically pure epoxy vinyl sulfoxides 10-13 a nd 15 undergo highly regio-and stereoselective S(N)2' displacements wi th alkyl cyanocuprates. The sulfinyl auxiliary controls the anti-syn s tereochemistry of the process. Copyright (C) 1996 Elsevier Science Ltd