INDUCED DECOMPOSITION OF ACETYLENIC PEROX IDES

Authors
LEMEE L BOURGEOIS MJ MONTAUDON E
Citation
L. Lemee et al., INDUCED DECOMPOSITION OF ACETYLENIC PEROX IDES, Bulletin des Societes chimiques belges, 105(8), 1996, pp. 467-472
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Bulletin des Societes chimiques belges → ACNP
ISSN journal
00379646
Volume
105
Issue
8
Year of publication
1996
Pages
467 - 472
Database
ISI
SICI code
0037-9646(1996)105:8<467:IDOAPI>2.0.ZU;2-K
Abstract
Acetylenic peroxides react as radicals in good hydrogen-donor solvents . Addition to the triple bond leads to monoadducts and attack on the O -O bond gives unsaturated acetals. The intermediate vinyl radical obta ined in the first case does not seem to lead to homolytic intramolecul ar substitution. Unlike their ethylenic homologous these compounds are not unsaturated heterocycle precursors.