SYNTHESIS OF METAL SILICIDE POWDERS BY THERMOLYSIS OF METAL CHLORIDESWITH MAGNESIUM SILICIDE

Authors
FITZMAURICE JC HECTOR AL PARKIN IP ROWLEY AT
Citation
Jc. Fitzmaurice et al., SYNTHESIS OF METAL SILICIDE POWDERS BY THERMOLYSIS OF METAL CHLORIDESWITH MAGNESIUM SILICIDE, Phosphorus, sulfur and silicon and the related elements, 101(1-4), 1995, pp. 47-55
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
101
Issue
1-4
Year of publication
1995
Pages
47 - 55
Database
ISI
SICI code
1042-6507(1995)101:1-4<47:SOMSPB>2.0.ZU;2-B
Abstract
Thermolysis (850 degrees C) of a mixture of Mg2Si and MCl(n) (M = Y, G d, Dy, Ho, Ti, Zr, Hf, Nb, Ta, Mo, W, Fe, Pr; n = 3, 4, 5) produces me tal silicides M(x)Si(y) as microcrystalline powders. The reactions giv e a useful insight into the mechanisms working in this type of reactio n.