STUDY ON KABACHNIK-FIELD AND MOEDRITZER-I RANI REACTIONS .1. REACTIONOF TRANS-DIAMINO-1,2-CYCLOHEXANE

Authors
BAILLY T BURGADA R
Citation
T. Bailly et R. Burgada, STUDY ON KABACHNIK-FIELD AND MOEDRITZER-I RANI REACTIONS .1. REACTIONOF TRANS-DIAMINO-1,2-CYCLOHEXANE, Phosphorus, sulfur and silicon and the related elements, 101(1-4), 1995, pp. 131-140
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
101
Issue
1-4
Year of publication
1995
Pages
131 - 140
Database
ISI
SICI code
1042-6507(1995)101:1-4<131:SOKAMR>2.0.ZU;2-O
Abstract
The Kabachnik-Fields and Moedritzer-Irani reactions are studied in the case of 1-2 diamino trans cyclohexane dl as aminated component. The n ew bicyclic bis phosphonates 1, 1', la have been obtained in the first case and the tetra phosphonic acid 2' in the second one. The methylen e bridge between the two nitrogen atoms in 1 and la is a protecting gr oup that is stable in basic medium and readily removed at 20 degrees C in acidic conditions. The H-1, C-13 and P-31 spectra are reported for all new compounds.