LITHIATIONS OF 1-ALKYL-1H-1,2,4-TRIAZOL-5-YL SILANES - NOVEL ANION-MEDIATED CARBON-TO-CARBON SILICON MIGRATIONS

Authors
ANDERSON DK CURTIS JM SIKORSKI JA
Citation
Dk. Anderson et al., LITHIATIONS OF 1-ALKYL-1H-1,2,4-TRIAZOL-5-YL SILANES - NOVEL ANION-MEDIATED CARBON-TO-CARBON SILICON MIGRATIONS, Phosphorus, sulfur and silicon and the related elements, 101(1-4), 1995, pp. 291-293
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
101
Issue
1-4
Year of publication
1995
Pages
291 - 293
Database
ISI
SICI code
1042-6507(1995)101:1-4<291:LO1S-N>2.0.ZU;2-C
Abstract
The lithiation chemistry of several 1-alkyl-1H-1,2,4-triazol-5-yl sila nes has been investigated. Lithiation occurs exclusively on the 1-alky l group, a to nitrogen, and on warming, an unusual anion-mediated carb on-to-carbon silicon migration occurs giving rise to novel 1H-1,2,4-tr iazol-1-yl alkyl silanes.