Natural films on the ocean surface influence air-sea fluxes of momentu
m, heat and gas. It is therefore essential to be able to map the geogr
aphical extent and variability of such films to determine the resultin
g impact on the earth's climate system. Satellite based Synthetic Aper
ture Radar (SAR) may prove very useful, and perhaps the only way, to q
uantify global scale film distribution. In order to investigate the co
mposition of natural film and its effect on radar return, in situ samp
les of the surface microlayer were for the first time taken simultaneo
usly with ERS-1 SAR coverage of the sea. Our results show that the fil
m was enriched in organic composition and that the concentration of fa
tty acids was generally one order of magnitude higher inside than outs
ide natural film areas, resulting in a 6-17 dB decrease in radar backs
catter.