LOW-WATER-CONTENT DIAZOMETHANE-D(2) AND ITS ISOTOPIC ASSAY

Authors
STRAZZOLINI P GIUMANINI AG VERARDO G
Citation
P. Strazzolini et al., LOW-WATER-CONTENT DIAZOMETHANE-D(2) AND ITS ISOTOPIC ASSAY, Bulletin of the Chemical Society of Japan, 69(10), 1996, pp. 2943-2946
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
69
Issue
10
Year of publication
1996
Pages
2943 - 2946
Database
ISI
SICI code
0009-2673(1996)69:10<2943:LDAIIA>2.0.ZU;2-B
Abstract
A multiple D2O-CH2N2 exchange followed by a final anhydrification with K2CO3 gave an alcohol-free low-water-content ether solution of CD2N2. Procedural improvements for the exchange are reported. The extent of deuteration with a quantitative evaluation of the actual species prese nt in any solution of diazomethane could be determined by a GC-MS anal ysis and H-1 NMR spectrometry on a suitable derivative. In addition, a procedure for the quantitative determination of water in diazomethane solutions has been developed.