H. Abid et al., ELECTRONIC-STRUCTURE AND OPTICAL-PROPERTIES OF THE QUATERNARY ALLOY GA1-XALXASYSB1-Y, Materials science & engineering. B, Solid-state materials for advanced technology, 41(3), 1996, pp. 314-321
A method for calculating the electronic structure of the quaternary al
loy GaAlAsSb is presented. We have used the empirical pseudopotential
method coupled with the virtual crystal approximation (VCA). which inc
orporates the compositional disorder as an effective potential. The el
ectronic structures are studied for GaAlAsSb (x = 0.5, y = 0.6) and Ga
AlAsSb lattice matched tu GaSb as well as InAs. In the case of GaSb la
ttice matched quaternary alloy, the bowing parameter for the Gamma poi
nt gap is in good agreement with experimental results. In addition, a
method for calculating the refractive indices at energies below the di
rect band edge is presented. The photon energies dependence of the ref
ractive index is calculated with the model of diielectric constants of
semiconductors based on simplified models of the interband transition
s. Also the composition dependence of the refractive index is discusse
d, the result indicates that the refractive index increases with alloy
ing for the quaternary alloy GaAlAsSb lattice matched to GaSb.