AN EFFICIENT SYNTHETIC ROUTE TO PRIMARY AND SECONDARY CONDENSATION PRODUCTS OF SILANETRIOLS STARTING FROM (ARYLAMINO)TRICHLOROSILANES

Authors
MURUGAVEL R BOTTCHER P VOIGT A WALAWALKAR MG ROESKY HW PARISINI E TEICHERT M NOLTEMEYER M
Citation
R. Murugavel et al., AN EFFICIENT SYNTHETIC ROUTE TO PRIMARY AND SECONDARY CONDENSATION PRODUCTS OF SILANETRIOLS STARTING FROM (ARYLAMINO)TRICHLOROSILANES, Chemical communications, (21), 1996, pp. 2417-2418
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
21
Year of publication
1996
Pages
2417 - 2418
Database
ISI
SICI code
1359-7345(1996):21<2417:AESRTP>2.0.ZU;2-5
Abstract
Stoichiometry dependent hydrolysis of (arylamino)silyltrichlorides usi ng anhydrous N2H4 as the HCl acceptor and dehydrating agent leads to t he formation of the primary and secondary condensation products of sil anetriols, tetrahydroxydisiloxanes [Ar(SiMe(3))NSi(OH)(2)]O-2 and cycl otrihydroxytrisiloxanes [Ar(SiMe(3))NSi(OH)O](3), respectively,