REACTION OF [W(ETA(2)-PHC(2)PH)(3)(NCME)] WITH O-DIPHENYLPHOSPHINO-STYRENE AND O-DIPHENYLPHOSPHINO-ALLYLBENZENE - EVIDENCE FOR NOVEL CARBON-CARBON DOUBLE AND TRIPLE BOND-CLEAVAGE AND ALKYNE INSERTION REACTIONS

Authors
CAIRNS GA CARR N GREEN M MAHON MF
Citation
Ga. Cairns et al., REACTION OF [W(ETA(2)-PHC(2)PH)(3)(NCME)] WITH O-DIPHENYLPHOSPHINO-STYRENE AND O-DIPHENYLPHOSPHINO-ALLYLBENZENE - EVIDENCE FOR NOVEL CARBON-CARBON DOUBLE AND TRIPLE BOND-CLEAVAGE AND ALKYNE INSERTION REACTIONS, Chemical communications, (21), 1996, pp. 2431-2432
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
21
Year of publication
1996
Pages
2431 - 2432
Database
ISI
SICI code
1359-7345(1996):21<2431:RO[WO>2.0.ZU;2-D
Abstract
Reaction of [W(eta(2)-PhC(2)Ph)(3)(NCMe)] with o-diphenyl-phosphino-st yrene or -allylbenzene leads to either novel reorganisation reactions involving cleavage of carbon-carbon double and triple bonds, or unusua l insertion reactions by PhC(2)Ph into carbon-hydrogen bonds.