Hr. Hudson et al., INTERACTION OF TRIETHYL PHOSPHITE WITH 3-FLUOROPROPANOYL CHLORIDE - THE CONCURRENT FORMATION OF 1 2-REACTION-PRODUCTS AND 2/1-REACTION-PRODUCTS/, Chemical communications, (21), 1996, pp. 2445-2446
The major products of the interaction between triethyl phosphite and 3
-fluoropropanoyl chloride at room temperature are diethyl fluoropropan
oyloxy)-3-fluoroprop-1-enylphosphonate 3 and diethyl 1-(diethoxyphosph
oryl)-3-fluoropropyl phosphate 4, which result from concurrent 1:2 and
2:1 reactions, respectively.