SAMARIUM-MEDIATED REDISTRIBUTION OF SILANES AND FORMATION OF TRINUCLEAR SAMARIUM-SILICON CLUSTERS

Authors
RADU NS HOLLANDER FJ TILLEY TD RHEINGOLD AL
Citation
Ns. Radu et al., SAMARIUM-MEDIATED REDISTRIBUTION OF SILANES AND FORMATION OF TRINUCLEAR SAMARIUM-SILICON CLUSTERS, Chemical communications, (21), 1996, pp. 2459-2460
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
21
Year of publication
1996
Pages
2459 - 2460
Database
ISI
SICI code
1359-7345(1996):21<2459:SROSAF>2.0.ZU;2-L
Abstract
The samarium complex Cp(2)SmCH(SiMe(3))(2) (Cp* = C(5)Me(5)), unlike the related alkyls Cp(2)LnCH(SiMe(3))(2) (Ln = Y, Nd), mediates the r edistribution of hydrosilanes while being converted to trisamarium clu sters, including -3(mu-SiH3)(mu(3)-eta(1),eta(1),eta(2)-SiH2-SiH2).