REDETERMINATION OF THE STRUCTURE OF LA2CU2O5 BY NEUTRON POWDER DIFFRACTION

Citation
Nr. Khasanova et al., REDETERMINATION OF THE STRUCTURE OF LA2CU2O5 BY NEUTRON POWDER DIFFRACTION, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2381-2384
Citations number
15
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
10
Pages
2381 - 2384
Database
ISI
SICI code
0108-2701(1996)52:<2381:ROTSOL>2.0.ZU;2-O
Abstract
Dicopper(II) dilanthanum pentaoxide, La2Cu2O5, has been prepared using a high-pressure technique. Its structure at 296 and 10 K was analysed by Rietveld refinements using neutron powder diffraction data. The st ructure of La2Cu2O5 comprises CuO5 square pyramids connected to each o ther in three dimensions by corner sharing and ten-coordinate La3+ ion s occupying positions next to oxygen vacancies which form tunnels alon g the c axis.