BIS(ETA(5)-HYDROPENTALENYL)IRON

Authors
MOLINS E MANIUKIEWICZ W MIRAVITLLES C MAS M MANRIQUEZ JM CHAVEZ I OELCKERS B FARRAN J BRIANSO JL
Citation
E. Molins et al., BIS(ETA(5)-HYDROPENTALENYL)IRON, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2414-2416
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
10
Pages
2414 - 2416
Database
ISI
SICI code
0108-2701(1996)52:<2414:B>2.0.ZU;2-N
Abstract
In the structure of bis[(3a,4,5,6,6a-eta))- 1-hydropentalenyl]iron, [F e(C8H7)(2)], the two pentalene ligands are parallel. The molecules are packed in chains along the a axis and there are no significant interm olecular interactions, The compound shows disorder at the iron positio n with a 93.3% major and a 6.7% minor component, The structure of the predominant component has been determined. In addition, the double bon d in one pentalene ligand is disordered. This confirms the results of a previous spectroscopic H-1 NMR study.