BIS(1,2-DI-4-PYRIDYLETHANE-N-N')CADMIUM(II) TETRACYANONICKELATE(II) M-XYLENE SOLVATE

Citation
B. Gunes et al., BIS(1,2-DI-4-PYRIDYLETHANE-N-N')CADMIUM(II) TETRACYANONICKELATE(II) M-XYLENE SOLVATE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2425-2427
Citations number
11
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
10
Pages
2425 - 2427
Database
ISI
SICI code
0108-2701(1996)52:<2425:BTM>2.0.ZU;2-Z
Abstract
The title compound, bis(1,2-di-4-pyridylethane-N:N')-cadmium(II) tetra cyanonickelate(II) di-m-xylene solvate, [Cd(C12H12N2)(2)] [Ni(CN)(4)]. 2C(8)H(10), is represented by the general Hofmann-type clathrate formu la Cd-(Ligand)(2)Ni(CN)(4).2Guest, where Ligand is 1,2-di-4-pyridyleth ane (C12H12N2) and Guest is m-xylene (C8H10). It was seen that the str ucture of the title compound is of a new type and quite different from that of the Hofmann-type clathrates.