MOLECULAR ADDUCTS OF INORGANIC SALTS .7. CD(REO4)(2-CENTER-DOT)4TU (TU EQUALS THIOUREA)

Authors
PETROVA R ANGELOVA O BAKARDJIEVA S MACICEK J
Citation
R. Petrova et al., MOLECULAR ADDUCTS OF INORGANIC SALTS .7. CD(REO4)(2-CENTER-DOT)4TU (TU EQUALS THIOUREA), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2432-2434
Citations number
19
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
10
Pages
2432 - 2434
Database
ISI
SICI code
0108-2701(1996)52:<2432:MAOIS.>2.0.ZU;2-X
Abstract
The crystal structure of cadmium tetraoxorhenium tetrakis(thiourea), C d(ReO4)(2) . 4CH(4)N(2)S, is comprised of isolated trans-[Cd(ReO4)(2)t u(4)] clusters consisting of a CdS4O2 octahedron and two ReO4 tetrahed ra. The Cd-S-C-N torsion angles are -22.6(5) and 69.1(4)degrees for th e two thiourea molecules which are inclined at an angle of 10.8(5)degr ees with respect to one another. The structural units are held togethe r by a complex network of hydrogen bonds.