2,2'-BIPYRIAYL-N,N')(THIODIACETATO-O,O',S)ZINC(II) TETRAHYDRATE

Authors
BAGGIO R PEREC M GARLAND MT
Citation
R. Baggio et al., 2,2'-BIPYRIAYL-N,N')(THIODIACETATO-O,O',S)ZINC(II) TETRAHYDRATE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2457-2460
Citations number
14
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
10
Pages
2457 - 2460
Database
ISI
SICI code
0108-2701(1996)52:<2457:2T>2.0.ZU;2-E
Abstract
The title complex, ipyridyl-N,N')(3-thiapentanedioate-O,S,O')zinc(II) tetrahydrate, [Zn(C4H4O4S)(C10H8N2)(H2O)].4H(2)O, is mononuclear with a coordination sphere consisting of one S, two N and three O atoms. Th e Zn atom is linked to a tridentate thiodiacetate ligand, a bidentate 2,2'-bipyridine ligand and an aqua ligand resulting in a slightly dist orted octahedral coordination geometry. The molecular units are linked together in the crystal by an extensive hydrogen-bonding network and by intermolecular S ... S interactions.