Light emission has been detected at the tip-sample junction of a Scann
ing Tunneling Microscope (S.T.M.) in air on noble metallic surfaces. A
spectroscopic study of emitted photons for Au-Au and PtIr-Au tunnelin
g junctions is presented. The general aspect of the spectra depends on
the materials used in the junctions; a study of the spectra as a func
tion of tunneling current and surface bias voltage reveals similar and
reproducible characteristics.