Polarization dependent photoluminescence and photocurrent measurements
were carried out on undoped and sulfur doped single crystals of CdSiA
s2. For undoped crystal the interband transition A shows a 40 meV blue
shift under perpendicular light polarization with respect to the paral
lel one. This shift is about twice as large for sulfur doped crystal.
A pronounced photoabsorption band at 1.53 eV, related to the sulfur do
nor, is observed in the low temperature photocurrent spectrum. A signi
ficant enhancement of the optical anisotropy of donor-acceptor transit
ion is seen in the low temperature photoluminescence spectra of CdSiAs
2 doped with sulfur. (C) 1996 American Institute of Physics.