P. Chowdhury et al., IMPROVEMENT OF ULTRATHIN GATE OXIDE AND OXYNITRIDE INTEGRITY USING FLUORINE IMPLANTATION TECHNIQUE, Applied physics letters, 70(1), 1997, pp. 37-39
The effects of fluorine on ultrathin gate oxide and oxynitride (simila
r to 40 Angstrom) have been studied. The incorporation of fluorine was
done by fluorine ion implantation into polycrystalline silicon (polys
ilicon) gate followed by a high-temperature drive-in step. It has been
found that the integrity of oxide has been improved with the incorpor
ation of fluorine as demonstrated by the reduction of stress-induced l
eakage current and interface trap generation, Furthermore, unlike thic
ker dielectrics (>100 Angstrom) for which the charge-to-breakdown (Q(B
D)) values decrease with increasing fluorine concentration, Q(BD)'s re
main the same as those of the control samples for the ultrathin thickn
ess regime, The mechanism for oxide quality improvement by F will also
be discussed in the letter. (C) 1997 American Institute of Physics.