4-LAYER COMPLEXATION MODEL FOR ION ADSORPTION AT ELECTROLYTE OXIDE INTERFACE - INTERRELATIONS OF MODEL PARAMETERS/

A profound theoretical analysis is presented of the four layer complex ation model assuming that adsorbed anions and cations are located in t wo distinct layers, The theoretical relations between the intrinsic co mplexation constants. developed in our previous paper (Langmuir 1995, 22, 3199) are subjected to an exhaustive numerical analysis, along wit h the newly developed relation between PZC and IEP. That analysis show s that the dependence of the electrical capacitances in the system on the activity of the bulk electrolyte is of crucial importance for the behavior of these systems.