PREDICTION OF SPUR OVERLAP TIME, RADICAL YIELD PROFILES, AND DECOMPOSITION OF TRICHLOROETHYLENE INDUCED BY VARIOUS PULSE TYPES OF ELECTRON-BEAM

Authors
KIM DW HAN KC LEE WK IHM SK
Citation
Dw. Kim et al., PREDICTION OF SPUR OVERLAP TIME, RADICAL YIELD PROFILES, AND DECOMPOSITION OF TRICHLOROETHYLENE INDUCED BY VARIOUS PULSE TYPES OF ELECTRON-BEAM, Radiation physics and chemistry, 48(5), 1996, pp. 651-657
Citations number
16
Categorie Soggetti
Nuclear Sciences & Tecnology","Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Radiation physics and chemistry → ACNP
ISSN journal
0969806X
Volume
48
Issue
5
Year of publication
1996
Pages
651 - 657
Database
ISI
SICI code
0969-806X(1996)48:5<651:POSOTR>2.0.ZU;2-2
Abstract
A kinetic model was suggested to compute the yield profiles of primary radicals generated from water radiolysis. For various cases including pulse radiolysis and steady irradiation time of spur overlap was comp uted in order to ensure homogeneity over the entire system. As a resul t, consistency to roughly first order kinetics was resulted for decomp osition of 1 ppm trichloroethylene (TCE) and slight deviation from the linear model was predicted for 10 ppm TCE. Copyright (C) 1996 Elsevie r Science Ltd