MEASUREMENT OF ENTHALPY DIFFERENCES IN CRYOSOLUTIONS - INFLUENCE OF THERMAL-EXPANSION

Authors
VANDERVEKEN BJ
Citation
Bj. Vanderveken, MEASUREMENT OF ENTHALPY DIFFERENCES IN CRYOSOLUTIONS - INFLUENCE OF THERMAL-EXPANSION, Journal of physical chemistry, 100(44), 1996, pp. 17436-17438
Citations number
6
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
100
Issue
44
Year of publication
1996
Pages
17436 - 17438
Database
ISI
SICI code
0022-3654(1996)100:44<17436:MOEDIC>2.0.ZU;2-1
Abstract
Cryosolvents such as liquid nitrogen, argon, krypton, and xenon show a substantial thermal expansion. Its influence on the value of enthalpy differences for simple chemical equilibria in dilute solutions in suc h solvents, determined using infrared spectroscopy, is discussed. Corr ections to account for the thermal expansion are proposed.