CHIRAL 1,2,1'-TRISUBSTITUTED FERROCENES - ACCESS TO CHIRAL OXAFERROCENOPHANES

Authors
IFTIME G DARAN JC MANOURY E BALAVOINE GGA
Citation
G. Iftime et al., CHIRAL 1,2,1'-TRISUBSTITUTED FERROCENES - ACCESS TO CHIRAL OXAFERROCENOPHANES, Organometallics, 15(22), 1996, pp. 4808-4815
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
22
Year of publication
1996
Pages
4808 - 4815
Database
ISI
SICI code
0276-7333(1996)15:22<4808:C1F-AT>2.0.ZU;2-W
Abstract
Combining the Kagan method for synthesis of chiral 2-substituted ferro cenecarbaldehydes with our recent method for synthesis of 1'-substitut ed formylferrocenes, we found easy access to various practically enant iomerically pure ferrocenecarbaldehydes substituted in the 2- and 1'-p ositions. Furthermore, we have described a general method of synthesis of chiral ferrocenophanes. The X-ray crystal structures for three of them were determined.