SYNTHESIS OF AROMATIC 1,2-DIAZINES BY INVERSE ELECTRON DEMAND DIELS-ALDER REACTION OF POLYMER-SUPPORTED 1,2,4,5-TETRAZINES

Authors
PANEK JS ZHU B
Citation
Js. Panek et B. Zhu, SYNTHESIS OF AROMATIC 1,2-DIAZINES BY INVERSE ELECTRON DEMAND DIELS-ALDER REACTION OF POLYMER-SUPPORTED 1,2,4,5-TETRAZINES, Tetrahedron letters, 37(45), 1996, pp. 8151-8154
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
45
Year of publication
1996
Pages
8151 - 8154
Database
ISI
SICI code
0040-4039(1996)37:45<8151:SOA1BI>2.0.ZU;2-G
Abstract
Inverse electron demand Diels-Alder reactions of unsymmetrically subst ituted 1,2,4,5-tetrazines immobilized on a solid support participate i n thermally promoted cycloadditions with a wide range of electron-rich dienophiles. The reactions afford functionalized 1,2-diazines bearing a sulfur-based leaving group (-SR or -SO(2)R) at the C-6 position. Co pyright (C) 1996 Elsevier Science Ltd