SYNTHESIS AND REACTIVITY OF A FLUORINATED DIENOPHILE

Authors
CROWLEY PJ PERCY JM STANSFIELD K
Citation
Pj. Crowley et al., SYNTHESIS AND REACTIVITY OF A FLUORINATED DIENOPHILE, Tetrahedron letters, 37(45), 1996, pp. 8237-8240
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
45
Year of publication
1996
Pages
8237 - 8240
Database
ISI
SICI code
0040-4039(1996)37:45<8237:SAROAF>2.0.ZU;2-I
Abstract
hylcarbamoyloxy-2-fluoro-2-(phenylsulfonyl)-ethene has been prepared a nd reacted with a variety of dienes to give fluorinated [4+2] cycloadd ucts. In contrast the desulfonated equivalent 1-(N,N-diethylcarbamoylo xy)-2-fluoro-E-ethene reacts with cyclopentadiene alone, to give mixtu res of [4+2] and [2+2] cycloadducts. Copyright (C) 1996 Elsevier Scien ce Ltd.