Hl. Bai et al., ENHANCEMENT OF THE REFLECTIVITY OF SOFT-X-RAY CO C MULTILAYERS AT GRAZING-INCIDENCE BY THERMAL-TREATMENT/, Journal of physics. Condensed matter, 8(45), 1996, pp. 8763-8776
We report a significant increase in the reflectivity of a soft x-ray C
o/C multilayer at grazing incidence after low-temperature annealing. B
y monitoring the enhancement of the first-order modulation peak on ann
ealing, an effective interdiffusion coefficient as low as -10(-25) m(2
) s(-1) has been measured, which is nearly equal to the true macroscop
ic interdiffusion coefficient as the modulation wavelength of the Co/C
multilayer studied is well above the critical wavelength. The negativ
e true macroscopic interdiffusion coefficient indicates that there is
a tendency to phase separation in the Co-C system, which can be interp
reted as the positive enthalpy of mixing calculated on the basis of Mi
edema's macroscopic atom model. The decrease in reflectivity above som
e annealing temperature is also discussed and explained as the competi
tion between interfacial sharpness and roughness. This is the first re
port of observations of enhanced reflectivity in the Co/C multilayered
system.