Particulate characteristics were investigated for AlN synthesized by a
thermochemical reaction of aluminium aerosol with ammonia gas. The pr
oduct powders had a decreasing specific surface area between 15.7 and
36.7 m(2)g(-1), with increasing reaction temperature from 1100-1500 de
grees C, and the powders with large surface area were strongly hygrosc
opic. Although the powders were severely aggregated and had a small am
ount of unreacted aluminium, light milling and post heat treatment mad
e them ultrafine and completely converted. When sintered with 0.5% ytt
rium at 1900 degrees C, full densification and high thermal conductivi
ty of about 130 W m(-1)K(-1) were obtained.