Chalcogenide glasses with composition Ge20Se80-xTlx (x = 10, 15, 20, 2
5, 35 %) have been prepared by the usual melt-quenching technique. Thi
n films of the mentioned compositions have been prepared by the electr
on beam evaporation. In addition, another set taken from the compositi
on of X = 30 at % with different thicknesses (d = 14.7, 30.0, 56.5, 70
.0, 101.0, 180.0 nm) have been taken into consideration. The X-ray dif
fraction (XRD) analysis revealed the amorphous nature of the prepared
films. It was found that, in contrast to the optical gap (E(op)), both
the extent of the band tailing (B), and the band gap (E(e)) increase
with increasing thallium content. In other side, E(op) showed thicknes
s independency. The refractive index (n) showed obvious dependence on
both composition and thickness also on the energy of the incident radi
ation.