A normal incidence X-ray standing wave (NIXSW) study of room temperatu
re in-situ S adsorption on InP(110) is described. The S atom XSW profi
le was measured by detecting S 1s photoemission yield for the (220) Br
agg reflection. The average perpendicular distance of the S atoms from
the InP(110) surface was determined to be 1.95 +/- 0.02 Angstrom. The
coherent fraction f(c) was found to be 0.67 +/- 0.02, which upon anne
aling to 270 degrees C increased to 0.82 +/- 0.02. A (1 x 1) low energ
y diffraction (LEED) pattern was observed in all cases. Models for the
adsorption geometry are discussed.