Interfacial properties of Au/PNx/n-InP Schottky junctions and metal-in
sulator-semiconductor (MIS) diodes formed by a series of in-situ remot
e plasma processes have been evaluated by measuring electrical charact
eristics. The in-situ processes consist of removal of native oxide by
a H-2 plasma, surface modification by a PH3 plasma, deposition of a PN
x layer by the use of PH3 and N-2 plasma, and subsequent metal evapora
tion. An effective barrier height of 0.83 eV and a true barrier height
of 0.57 eV are observed for the tunnel MIS Schottky junction. An inte
rface state density as low as 1.4 x 10(11) eV(-1) cm(-2) is obtained f
or the MIS diodes. From the behavior of the true barrier height and th
e low interface state density, it is suggested that a novel in-situ pr
ocess is effective in forming an interface of PNx/InP structure.