Ss. Malhotra et al., NANOCRYSTALLINE HIGH COERCIVICY PRCO /CR THIN-FILMS - POTENTIAL HIGH-DENSITY MAGNETIC RECORDING MEDIA/, Journal of magnetism and magnetic materials, 161, 1996, pp. 316-322
PrCo thin films with a Cr underlayer (PrCo//Cr) have been prepared by
de magnetron sputtering, The as-deposited PrCo films with a Cr underla
yer of 80 nm have coercivity values of about 300 to 400 Oe but after a
nnealing at 400 degrees C for 20 min a large enhancement in the coerci
vity is observed, The coercivity of the PrCo films after annealing at
400 degrees C varies from 2 kOe to as high as 8 kOe depending on the f
ilm thickness and deposition conditions. The as-deposited PrCo//Cr fil
ms have a mostly amorphous PI Co layer but after annealing at 400 degr
ees C the PrCo layer is nearly 100% crystalline with a grain size of a
bout 10 nm as revealed by the high resolution TEM micrographs. The coe
rcivity of the films depends Strongly on the Ar pressure during sputte
ring of the PrCo layer, while the Ar pressure for the Cr underlayer do
es not significantly change the coercivity of the films, The Cr underl
ayer thickness was varied from 10 to 160 nm and only a slight change i
n coercivity was observed, The magnetic switching volume was estimated
by the dependence of apparent coercivity on the sweep rate of the mag
netic field and also through magnetic viscosity and remanence measurem
ents. The measured switching volume is of the order of 1 to 1.5 x 10(-
18) cm(3).