THERMAL BLANKET FOR IN-SITU REMEDIATION OF SURFICIAL CONTAMINATION - A PILOT TEST

Citation
Iet. Iben et al., THERMAL BLANKET FOR IN-SITU REMEDIATION OF SURFICIAL CONTAMINATION - A PILOT TEST, Environmental science & technology, 30(11), 1996, pp. 3144-3154
Citations number
15
Categorie Soggetti
Environmental Sciences","Engineering, Environmental
ISSN journal
0013936X
Volume
30
Issue
11
Year of publication
1996
Pages
3144 - 3154
Database
ISI
SICI code
0013-936X(1996)30:11<3144:TBFIRO>2.0.ZU;2-I
Abstract
Surficial PCB contamination has been successfully and safely removed f rom soils in a field test at the site of a former dragstrip where oil- containing PCBs had been sprayed to minimize airborne dust. Decontamin ation was achieved by electrically heating a 9.3-m(2) area under a the rmal blanket, and PCB concentrations were reduced from up to 2000 ppm to less than 2 ppm in 24 h of heating. Initial PCB concentration in so me of the more contaminated areas averaged 700 mg/kg from 0 to 7.5 cm deep and 100 mg/kg from 7.5 to 15 cm, with maximum concentrations as h igh as 2000 mg/kg at the surface. The thermal blanket was operated at temperatures ranging from 815 to 925 degrees C. It took about 20-24 h for a 15-cm depth to reach 200 degrees C, which was sufficient to redu ce the total PCB concentration to below the mandated 2 mg/kg cleanup l evels. The variation of times to reach the desired temperature is prin cipally related to soil water content. A vapor stream was drawn by vac uum from the thermal blanket at a rate of 550-1100 L(STP)/min. Vaporiz ed groundwater constitutes from 40% to 70% of the vapor stream at the beginning of each heating cycle and therefore displaces a significant fraction of the air, but enough remains for oxidation of waste stream hydrocarbons in an external thermal oxidizer. We also;tested 2.4 m x 6 m thermal blanket modules that could be assembled into large arrays t o treat extensive areas. A full-scale thermal blanket system designed to treat this site would consist of 20 modules assembled into 288 m(2) thermal treatment systems, which require 1.8 MW of power and operate on a three-part cycle: heat and treat soil cool, and move to a new tre atment area. Emissions from the blanket consist of organics, which are destroyed by passing through a flameless thermal oxidizer.