The present work describes an attractive and economically viable novel
separation technique using superabsorbing hydrophilic polymer gel for
dewatering an industrial o-toluidine-water emulsion. It is demonstrat
ed that the initial water content of 30% in the emulsion is reduced to
3% within 10 min by using a semicontinuous separation strategy, which
can have significant energy savings over the conventional distillatio
n process. The mechanism of water removal and the effect of the presen
ce of interfacial agents on the rate of water removal are also studied
.