Xd. Wang et al., THE EFFECTS OF DOPING ON THE SELECTIVITY AND RESPONSE-TIME OF FLUORIDE ION-SELECTIVE ELECTRODES, Australian Journal of Chemistry, 49(8), 1996, pp. 897-899
We report the effect of doping on the response time and hydroxide ion
interference of fluoride ion-selective electrodes made by using membra
nes consisting of single crystals of CeF3, LaF3 and NdF3, both undoped
and doped with divalent cations, and of mixed crystals of neodymium a
nd samarium fluorides (Nd0.95Sm0.05F3 and Nd0.86Sm0.14F3). Doping not
only increases the bulk conductivity of the membrane, but also reduces
both the response time and the hydroxide ion interference of the elec
trode. This behaviour is due to an increase in the number of Frenkel d
efects in the crystal membrane, an effect which increases the mobility
of the fluoride ion. It has also been established that doped single c
rystals of either LaF3 or NdF3 offer the best performance in terms of
selectivity.