THE UNIVERSALITY OF THE ELECTRON-SPIN RELAXATION IN C-60 MONO RADICAL-ANION SALTS - EPR STUDIES OF THE MODEL SYSTEM [P(C6H5)(4)](2)C(60)X

Authors
GOTSCHY B VOLKEL G
Citation
B. Gotschy et G. Volkel, THE UNIVERSALITY OF THE ELECTRON-SPIN RELAXATION IN C-60 MONO RADICAL-ANION SALTS - EPR STUDIES OF THE MODEL SYSTEM [P(C6H5)(4)](2)C(60)X, Applied magnetic resonance, 11(2), 1996, pp. 229-238
Citations number
27
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Applied magnetic resonance → ACNP
ISSN journal
09379347
Volume
11
Issue
2
Year of publication
1996
Pages
229 - 238
Database
ISI
SICI code
0937-9347(1996)11:2<229:TUOTER>2.0.ZU;2-6
Abstract
The C-60 radical anion salts [P(C6H5)(4)](2)C(60)X (X = Cl, Pr, I) are grown via electrocrystallization and used as a model system to study the electron spin and nuclear spin dynamics as well as the molecular d ynamics of C-60 mono anions in the solid state, which obey universal l aws. It is shown that [P(C6H5)(4)](2)C(60)X is an exception among the fullerides, since the temperature dependence of the JT distortion, pre dicted for ionic C-60, can be deduced.