Jr. Almirall et al., THE RECOVERY OF ACCELERANTS IN AQUEOUS SAMPLES FROM FIRE DEBRIS USINGSOLID-PHASE MICROEXTRACTION (SPME), Science & justice, 36(4), 1996, pp. 283-287
A popular method for the recovery of flammable and combustible liquid
residues from fire debris is passive headspace concentration using act
ivated charcoal strips (ACS) for the adsorption of the Liquid residues
followed by elution with carbon disulfide or other suitable solvent.
In comparison to the ACS extraction, the adaptation of SPME to the hea
dspace concentration of these residues from fire debris eliminates the
use of solvents, decreases the time needed for analysis and raises th
e sensitivity of the extraction. Presently, we report the use of SPME
for the rapid extraction of accelerants in aqueous solutions from fire
debris requiring minimal sample handling. Extremely low quantities of
pocket lighter fluid, gasoline and diesel fuel were directly extracte
d by SPME and their resulting gas chromatograms were accurately identi
fied.