A. Kawai et al., EFFECT OF DIELECTRIC PROPERTY OF HYDROUS DISPERSOID ON ELECTRORHEOLOGY, International journal of modern physics b, 10(23-24), 1996, pp. 2849-2855
The effect of the dielectric property was investigated of titania and
microcrystalline cellulose particles dispersed in a silicon oil on Ele
ctrorheology(ER). A commom understanding of the mechanism of ER is the
electrical interaction by the interfacial polarization of dispersed p
articles. Block et al. reported the relaxation frequency of ER fluids,
i. e. the rate of polarization, was very important to have an appreci
able ER effect. We found that the free water on the cellulose and the
titania particles dispersed in the silicon oil, which is respectively
dehydrated below the temperature of ca 110 and 300 degree centigrade,
was necessary for an appreciable ER effect. The relation was measured
between the water content and the dielectric properties such as dielec
tric constant epsilon' and dielectric loss factor epsilon '', as the w
ater adsorbed on the particles was estimated to alter the dielectric p
roperties of the ER fluid Both the dielectric constant and the relaxat
ion Frequency, which is defined by the applied frequency for a peak of
the dielectric loss factor, increased with the increase of the water
content. The relation was discussed between the ER effect and the diel
ectric properties.