A NEW ALKYL PEROXOVANADIUM CATALYST FOR SELECTIVE OXIDATION OF NITRILES TO ALPHA-OXO NITRILES - A FUNCTIONAL MIMIC OF CYT-P.450

Authors
CHOUDARY BM REDDY PN
Citation
Bm. Choudary et Pn. Reddy, A NEW ALKYL PEROXOVANADIUM CATALYST FOR SELECTIVE OXIDATION OF NITRILES TO ALPHA-OXO NITRILES - A FUNCTIONAL MIMIC OF CYT-P.450, Journal of molecular catalysis. A, Chemical, 112(3), 1996, pp. 385-388
Citations number
30
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis. A, Chemical → ACNP
ISSN journal
13811169
Volume
112
Issue
3
Year of publication
1996
Pages
385 - 388
Database
ISI
SICI code
1381-1169(1996)112:3<385:ANAPCF>2.0.ZU;2-P
Abstract
Alkyl peroxovanadium complex catalysed functionalisation of methylene of benzyl cyanides to afford peroxo nitriles or aroyl cyanides selecti vely depending on the molar quantities of oxidant, tert butyl hydroper oxide (t-BuOOH) used is described for the first time.