P. Leyrit et al., A NOVEL HETEROGENEOUS MOLECULAR CATALYST FOR THE MEERWEIN-PONNDORF-VERLEY AND OPPENAUER REACTIONS, Journal of molecular catalysis. A, Chemical, 112(3), 1996, pp. 395-400
The silica anchored mononuclear (tris)isopropoxyzirconium, (=SiO)Zr(Oi
-Pr)(3), is an efficient catalyst for the reduction of ketones and the
oxidation of alcohols by hydrogen transfer. Easy separation of the pr
oducts and recyclability of the catalyst are demonstrated.