S. Nakata et G. Groeninckx, A NEW THERMALLY-PROCESSABLE ARAMID AMORPHOUS NYLON BLEND WITH HIGH HEAT-RESISTANCE AND HIGH STIFFNESS/, Polymer, 37(23), 1996, pp. 5269-5273
Polymer blends based on a rigid-rod aramid poly (2-chloro-1,4-phenylen
e terephthalamide) (CIPPTA) and an amorphous nylon poly(hexamethylene
isophthalamide) (nylon 6I) were prepared by coprecipitation, and press
ed into films by hot-compression. By differential scanning calorimetry
(d.s.c.), optical microscopy and dynamic mechanical thermal analysis
(d.m.t.a.), formation of a co-continuous superstructure in the blend f
ilms was suggested. The blend films exhibited high heat resistance and
high stiffness, which are ascribable to the continuous aramid phase c
haracteristic of the co-continuous structure. Copyright (C) 1996 Elsev
ier Science Ltd.