PROPERTIES AND APPLICATIONS OF CARBON-FIBER DUAL-CYLINDER MICROELECTRODES

Authors
ZHANG CG ZHANG XJ YANG C ZHANG WM YAO B ZHOU XY
Citation
Cg. Zhang et al., PROPERTIES AND APPLICATIONS OF CARBON-FIBER DUAL-CYLINDER MICROELECTRODES, Electroanalysis, 8(10), 1996, pp. 947-951
Citations number
16
Categorie Soggetti
Chemistry Analytical
Journal title
Electroanalysis → ACNP
ISSN journal
10400397
Volume
8
Issue
10
Year of publication
1996
Pages
947 - 951
Database
ISI
SICI code
1040-0397(1996)8:10<947:PAAOCD>2.0.ZU;2-J
Abstract
A series of dual-cylinder microelectrodes with different interelectrod e gap were constructed with 7 mu m diameter carbon fibers. The collect ion-efficiency, feedback and shielding properties were studied in deta il with cyclic voltammetry and chronoamperometry for the case of the f errocyanide(III/II) couple. The effect of the collector potential on t he collection-efficiency and the currents at the anode and cathode ele ctrode were discussed. The application of these dual-cylinder microele ctrodes to determine the electrochemical reaction mechanism was demons trated.