K. Zurowski, CHANGES IN ION COMPOSITION IN THE LIQUID-SYSTEM CUCL2-KCL, INVESTIGATED BY THERMOGRAVIMETRY, Journal of thermal analysis, 47(3), 1996, pp. 775-790
CuCl2-KCl mixtures were annealed at 603 K and thermogravimetrically an
alysed after cooling to room temperature. The mixtures differed in the
molar ratio Cu/K and in the duration of heating at 603 K. The constit
utions of the ions, the reactions between them and the mechanisms of t
heir decomposition in the melt are proposed, as are the constitutions
of the active centres in the oxychlorination process.