We. Wentworth et al., EXPERIMENTAL AND THEORETICAL RELATIVE RESPONSE FACTORS FOR A PULSED DISCHARGE KRYPTON PHOTOIONIZATION DETECTOR, Journal of chromatography, 749(1-2), 1996, pp. 149-155
Citations number
4
Categorie Soggetti
Chemistry Analytical","Biochemical Research Methods
The relative photoionization cross sections (RePIX) have been determin
ed for a series of compounds normalized to benzene. The detectors are
doped (5.01% Kr) Kr-PDPID and pure helium(He-PDPID) pulsed discharge h
elium photoionization detectors. The pure helium detector is used to r
eference the responses. The magnitudes for the Kr-PDPID varied from ab
out 0.0 to 0.95. In order to understand the relative responses of thes
e compounds in the Kr-PDPID, the SCF-MO energy levels were calculated
for these compounds using HyperChem. Calculated vertical ionization po
tentials are compared with experimental adiabatic ionization potential
s.