ONE-BOND MN-55,C-13 COUPLING-CONSTANTS, A CORRECTION

Authors
RENTSCH D VONPHILIPSBORN W TOROCHESHNIKOV V
Citation
D. Rentsch et al., ONE-BOND MN-55,C-13 COUPLING-CONSTANTS, A CORRECTION, Magnetic resonance in chemistry, 34(11), 1996, pp. 955-957
Citations number
15
Categorie Soggetti
Spectroscopy,Chemistry
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
34
Issue
11
Year of publication
1996
Pages
955 - 957
Database
ISI
SICI code
0749-1581(1996)34:11<955:OMCAC>2.0.ZU;2-E
Abstract
Previously published one-bond Mn-55,C-13 coupling constants have been recalculated using a revised lineshape fitting program, QUADR. The acc uracy of the new data was confirmed by the simulation of quadrupole-br oadened but resolved C-13 and F-19 spectra of the model complexes K-3/ Co(CN)(6)/ and Li/AsF6/. The Mn-55, C-13 coupling constants lie in the range 128-189 Hz for Mn-CO bonds, 57-114 Hz for Mn-C(sp(2)) bonds and 35-79 Hz for Mn-C(sp(3)) bonds.