PECULIARITIES OF THE DIFFUSION OF SILVER AND SODIUM-IONS IN PHOSPHATE-GLASSES WITH A HIGH CONTENT OF NA2O

Citation
Vm. Syutkin et Va. Tolkatchev, PECULIARITIES OF THE DIFFUSION OF SILVER AND SODIUM-IONS IN PHOSPHATE-GLASSES WITH A HIGH CONTENT OF NA2O, Chemical physics, 212(1), 1996, pp. 149-156
Citations number
29
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
03010104
Volume
212
Issue
1
Year of publication
1996
Pages
149 - 156
Database
ISI
SICI code
0301-0104(1996)212:1<149:POTDOS>2.0.ZU;2-X
Abstract
The conductivity relaxation due to Na+ ions and the decay of radiation -induced centers controlled by Ag+ ion diffusion have been studied in phosphate glasses with a high content of Na2O. Both of the processes d isplay a nonexponential kinetic behavior and are satisfactorily descri bed by the Kohlrausch function. It has been demonstrated that on the m olecular level the Kohlrausch function should be interpreted as a sum of exponential decay functions with a distribution of relaxation times rather than the inherently nonexponential function.